Relaxations in Ba2BiSbO6 Double Complex Perovskite Ceramics

Authors

Manoel Carvalho Castro Jr.
Carlos William de Araujo Paschoal
Frank C. Snyder
Michael W. Lufaso, University of North FloridaFollow

Document Type

Article

Publication Date

11-15-2008

Abstract

The electric properties of the complex double perovskite Ba2BiSbO6 have been investigated using impedance spectroscopy in the frequency range from 1 Hz up to 1 MHz and in the temperature range from room temperature up to 560 K. There are two contributions to the electrical properties due to the grain and grain boundary. The oxygen vacancies play an important role in the conductivity and strongly increase the dielectric constant at high temperatures. The analysis of the frequency dependence of the conductivity clearly shows the structural phase transition of this compound near 515 K.

Comments

Originally published in Journal of Applied Physics 2008, 104, 104114

http://dx.doi.org/10.1063/1.3026654

Recommended Citation

Castro, Manoel Carvalho Jr.; Paschoal, Carlos William de Araujo; Snyder, Frank C.; and Lufaso, Michael W., "Relaxations in Ba2BiSbO6 Double Complex Perovskite Ceramics" (2008). Chemistry Faculty Research and Scholarship. 8.
https://digitalcommons.unf.edu/achm_facpub/8

Rights Statement

http://rightsstatements.org/vocab/InC/1.0/