Structural and Magnetic Variations in a Family of Isoskeletal, Oximate-Bridged {MnIV2MIII} Complexes (MIII=Mn, Gd, Dy)

Document Type

Article

Publication Date

2-21-2018

Abstract

The self-assembly reaction of MnCl2⋅4H2O, acenaphthenequinone dioxime (acndH2) and NEt3 has yielded an unprecedented, linear {MnIV2MnIII} complex with an S=5 spin ground state and non-SMM behavior. The targeted replacement of the central MnIII ion with GdIII and DyIII ions has successfully increased the S and turned on the SMM dynamics without affecting the core structure and the nature of the magnetic exchange interactions.

Publication Title

Chemistry - A European Journal

Volume

24

Issue

11

First Page

2588

Last Page

2592

Digital Object Identifier (DOI)

10.1002/chem.201706098

PubMed ID

29315881

ISSN

09476539

E-ISSN

15213765

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