New ligands for uranium complexation: A stable uranyl dimer bearing 2,6-diacetylpyridine dioxime

Authors

Dimitris I. Alexandropoulos, Brock University
Eleni C. Mazarakioti, Brock University
Sergio A. Corrales, University of North Florida
Jacob T. Bryant, University of North Florida
Lev V. Gasparov, University of North FloridaFollow
Christos Lampropoulos, University of North Florida
Theocharis C. Stamatatos, Brock University

Document Type

Article

Publication Date

4-1-2017

Abstract

The synthesis, characterization, and stability study of the first uranium complex bearing 2,6-diacetylpyridine dioxime (dapdoH2) is reported. The dimeric complex [UO2(dapdoH)Cl]2 is stable in solution as shown by ESI-MS and NMR spectrometry, and its solid-state structure was further analyzed by X-ray crystallography, IR, Raman and luminescence studies.

Publication Title

Inorganic Chemistry Communications

Volume

78

First Page

13

Last Page

16

Digital Object Identifier (DOI)

10.1016/j.inoche.2017.01.021

ISSN

13877003

Citation Information

Alexandropoulos, Mazarakioti, E. C., Corrales, S. A., Bryant, J. T., Gasparov, L. V., Lampropoulos, C., & Stamatatos, T. C. (2017). New ligands for uranium complexation: A stable uranyl dimer bearing 2,6-diacetylpyridine dioxime. Inorganic Chemistry Communications, 78, 13–16. https://doi.org/10.1016/j.inoche.2017.01.021