New ligands for uranium complexation: A stable uranyl dimer bearing 2,6-diacetylpyridine dioxime
The synthesis, characterization, and stability study of the first uranium complex bearing 2,6-diacetylpyridine dioxime (dapdoH2) is reported. The dimeric complex [UO2(dapdoH)Cl]2 is stable in solution as shown by ESI-MS and NMR spectrometry, and its solid-state structure was further analyzed by X-ray crystallography, IR, Raman and luminescence studies.
Inorganic Chemistry Communications
Digital Object Identifier (DOI)
Alexandropoulos, Mazarakioti, E. C., Corrales, S. A., Bryant, J. T., Gasparov, L. V., Lampropoulos, C., & Stamatatos, T. C. (2017). New ligands for uranium complexation: A stable uranyl dimer bearing 2,6-diacetylpyridine dioxime. Inorganic Chemistry Communications, 78, 13–16. https://doi.org/10.1016/j.inoche.2017.01.021