1-Aryltriazenes in the Suzuki, Heck, and Sonogashira Reactions in Imidazolium-ILs, with [BMIM(SO3H)][OTf] or Sc(OTf)3 as Promoter, and Pd(OAc)2 or NiCl2·glyme as Catalyst
Document Type
Article
Publication Date
9-22-2019
Abstract
1-Aryltriazenes, the protected and more stable form of aryl-diazonium species, can be conveniently unmasked with Brønsted acidic-IL or Sc(OTf)3 and coupled with a host of aryl/heteroaryl boronic acids, styrenes, and aryl/alkyl acetylenes in the Suzuki, Heck and Sonogashira reactions in one-pot and in respectable isolated yields, by using palladium or nickel catalyst in readily available imidazolium ILs as solvent, under mild conditions. The scope of these reactions are explored, and the potential for recovery/reuse of the IL solvent is also addressed.
Publication Title
European Journal of Organic Chemistry
Volume
2019
Issue
35
First Page
6088
Last Page
6093
Digital Object Identifier (DOI)
10.1002/ejoc.201901070
ISSN
1434193X
E-ISSN
10990690
Citation Information
Sutar, S. M., Savanur, H.M., Malunavar, S.S., Prabhala, P., Kalkhambkar, R.G., Laali, K.K. (2019) 1-Aryltriazenes in the Suzuki, Heck, and Sonogashira Reactions in Imidazolium-ILs, with [BMIM(SO3H)][OTf] or Sc(OTf)3 as Promoter, and Pd(OAc)2 or NiCl2·glyme as Catalyst. European Journal of Organic Chemistry, 2019(35), 6088-6093.